Here is a list of the podcasts available on Free Language:

Learn Arabic Podcasts
Learn Cantonese Podcasts
Learn English Podcasts
Learn French Podcasts
Learn German Podcasts
Learn Hindi Podcasts
Learn Italian Podcasts
Learn Japanese Podcasts
Learn Mandarin Chinese Podcasts
Learn Portuguese Podcasts
Learn Russian Podcasts
Learn Spanish Podcasts

Here is a list of the video podcasts, though not all languages have them yet:

Learn Arabic Video Podcasts
Learn Cantonese Video Podcasts
Learn English Video Podcasts
Learn French Video Podcasts
Learn German Video Podcasts
Learn Hindi Video Podcasts
Learn Italian Video Podcasts
Learn Japanese Video Podcasts
Learn Mandarin Chinese Video Podcasts
Learn Portuguese Video Podcasts
Learn Russian Video Podcasts
Learn Spanish Videos Podcasts